Gunda, HariniHariniGundaRay, Keith G.Keith G.RayKlebanoff, Leonard E.Leonard E.KlebanoffDun, ChaochaoChaochaoDunMarple, Maxwell A.T.Maxwell A.T.MarpleLi, SichiSichiLiSharma, PeterPeterSharmaFriddle, Raymond W.Raymond W.FriddleSugar, Joshua D.Joshua D.SugarSnider, Jonathan L.Jonathan L.SniderHorton, Robert D.Robert D.HortonDavis, Brendan C.Brendan C.DavisChames, Jeffery M.Jeffery M.ChamesLiu, Yi ShengYi ShengLiuGuo, JinghuaJinghuaGuoMason, Harris E.Harris E.MasonUrban, Jeffrey J.Jeffrey J.UrbanWood, Brandon C.Brandon C.WoodAllendorf, Mark D.Mark D.AllendorfJasuja, KabeerKabeerJasujaStavila, VitalieVitalieStavila2025-08-312025-08-312023-02-0810.1002/smll.2022054872-s2.0-85143992008https://d8.irins.org/handle/IITG2025/2575936470595Metal boride nanostructures have shown significant promise for hydrogen storage applications. However, the synthesis of nanoscale metal boride particles is challenging because of their high surface energy, strong inter- and intraplanar bonding, and difficult-to-control surface termination. Here, it is demonstrated that mechanochemical exfoliation of magnesium diboride in zirconia produces 3–4 nm ultrathin MgB<inf>2</inf> nanosheets (multilayers) in high yield. High-pressure hydrogenation of these multilayers at 70 MPa and 330 °C followed by dehydrogenation at 390 °C reveals a hydrogen capacity of 5.1 wt%, which is ≈50 times larger than the capacity of bulk MgB<inf>2</inf> under the same conditions. This enhancement is attributed to the creation of defective sites by ball-milling and incomplete Mg surface coverage in MgB<inf>2</inf> multilayers, which disrupts the stable boron–boron ring structure. The density functional theory calculations indicate that the balance of Mg on the MgB<inf>2</inf> nanosheet surface changes as the material hydrogenates, as it is energetically favorable to trade a small number of Mg vacancies in Mg(BH<inf>4</inf>)<inf>2</inf> for greater Mg coverage on the MgB<inf>2</inf> surface. The exfoliation and creation of ultrathin layers is a promising new direction for 2D metal boride/borohydride research with the potential to achieve high-capacity reversible hydrogen storage at more moderate pressures and temperatures.trueexfoliation | hydrogen storage | metal borides | metal borohydrides | multilayers | nanosheetsArticlehttps://escholarship.org/uc/item/1kg968g9161368298 February 2023192205487arJournal19WOS:000897610500001