Szymor-Pietrzak, DamianDamianSzymor-PietrzakKhan, Muhammad N.Muhammad N.KhanPagès, AnaïsAnaïsPagèsKumar, AjayAjayKumarDepner, NoahNoahDepnerClive, Derrick L.J.Derrick L.J.Clive2025-08-312025-08-312021-01-0110.1021/acs.joc.0c022842-s2.0-85097902619https://d8.irins.org/handle/IITG2025/23804meta-Aminophenols are formed by the action of DBU on 3-amino-2-chlorocyclohex-2-en-1-ones at room temperature in MeCN. The chloro compounds are generated by treating 3-aminocyclohex-2-en-1-ones with the easily prepared halogenating agent BnNMe3·ICl2 in MeOH-CH2Cl2. The amino group must carry two substituents, either two aryl, one aryl and one alkyl, or two alkyl groups; 3-aminocyclohex-2-en-1-ones of this type are readily made from cyclohex-2-en-1-one and a primary or secondary amine.falseArticle15206904619-6311 January 20217arJournal7