Dhakar, ShikhaShikhaDhakarKumar, RishabhRishabhKumarKhatua, RudranarayanRudranarayanKhatuaMitra, RahulRahulMitraUrkude, Rajashri R.Rajashri R.UrkudeGhosh, BiplabBiplabGhoshMondal, AnirbanAnirbanMondalBiswas, KrishanuKrishanuBiswasSharma, SudhanshuSudhanshuSharma2025-08-302025-08-302025-08-2110.1039/d5nr00937e2-s2.0-105013625970https://d8.irins.org/handle/IITG2025/2068040765408This study explores the enhancement of electrochemical CO<inf>2</inf> reduction (CO<inf>2</inf>ER) using a novel Cu nanoparticle decorated La<inf>0.8</inf>Sr<inf>0.2</inf>CoO<inf>3</inf> (LSCO) perovskite catalyst. The synthesized Cu/LSCO catalyst exhibits exceptional activity and selectivity for acetone production. A systematic variation in Cu loading revealed a non-linear trend in performance: faradaic efficiency (FE) increased from ∼40% for Cu 10/LSCO to a maximum of ∼93.7% for Cu 20/LSCO but significantly dropped to 7.5% for Cu 30/LSCO. Cu 20/LSCO also delivered a partial current density of −20.28 mA cm⁻², making it the most efficient composition. This behavior highlights the importance of optimal Cu loading, where enhanced nanoparticle dispersion and strong metal-support interaction (MSI) result in greater active site availability and improved catalytic performance. In contrast, excessive Cu loading leads to particle agglomeration, and diminished CO<inf>2</inf>ER activity. Cu 20/LSCO also exhibited stable performance over 40 000 seconds, demonstrating its potential for prolonged CO<inf>2</inf> electroreduction and highlighting its viability for sustainable CO<inf>2</inf> conversion in renewable energy applications. X-ray absorption spectroscopy (XAS) analysis confirmed the oxidation state and local coordination environment of Cu, providing critical mechanistic insight into the observed performance trend and the role of MSI. The Cu/LSCO catalyst, enhanced by metal-support interaction (MSI) along with the cell geometry, is an effective tool for high FE and liquid product selective electrocatalysis. Utilizing Cu or LSCO alone proves inefficient for CO<inf>2</inf>ER indicating the role of MSI. This strategy can be a stepping stone for developing electrocatalysts for direct multicarbon products at low overpotentials.falseArticle2040337219196-1920921 August 20250arJournal0WOS:001544440400001