Probing the peripheral role of amines in photo- And electrocatalytic H2production by molecular cobalt complexes

Dolui, DependuDependuDoluiMir, Ab QayoomAb QayoomMirDutta, ArnabArnabDutta2025-08-312025-08-312020-12-0710.1039/d0cc05786j2-s2.0-85096883745https://d8.irins.org/handle/IITG2025/2382133174879The incorporation of amine functionality in the periphery of a synthetic cobaloxime core induces excellent photo-(TON 180) and electrocatalytic H2 production (TOF 4330 s-1) in aqueous solution. The primary amine group displays a superior influence on the catalysis compared to a secondary amine group with an analogous cobaloxime template. This journal istrueProbing the peripheral role of amines in photo- And electrocatalytic H2production by molecular cobalt complexesArticlehttps://pubs.rsc.org/en/content/articlepdf/2020/cc/d0cc05786j1364548X14841-148447 December 202022arJournal24