Singh, SurajSurajSinghKumar, RohtashRohtashKumarDubey, Navneet NandgopalNavneet NandgopalDubeyAppayee, ChandrakumarChandrakumarAppayee2025-08-312025-08-312024-07-2310.1039/d4cc03132f2-s2.0-85199882647https://d8.irins.org/handle/IITG2025/2882139076133The first synthesis of chiral cis-2,5-disubstituted pyrrolidine organocatalysts is described. Their application for the enantioselective Michael addition of nitromethane to α,β-unsaturated aldehydes with excellent yield (up to 91%) and enantioselectivity (up to >99% ee) is demonstrated. Another catalytic application for the reaction of 2,4-hexadienal with nitrostyrene is also showcased.falseArticle1364548X8768-877123 July 20241arJournal2WOS:001280303700001