Multilayer arsenic mobilization and multimetal co-enrichment in the alluvium (Brahmaputra) plains of India: A tale of redox domination along the depth

The study attempts to understand arsenic (As) mobilization in a shallow aquifer with depth variation while focusing on the potential co-occurrence of As with priority metals (zinc and lead), using a pilot scale multilevel groundwater monitoring system (MGWS). Groundwater samples (n = 72) were collected bi-weekly (every 15 days) from the multilevel sampler (4.6, 9.2 and 13.8 m depths), installed at Tezpur, Sonitpur district of Brahmaputra floodplain (BFP), Assam, India, for a period of 1 year (August 2013–July 2014). Both geogenic and anthropogenic influences were found to affect the studied unconfined aquifer. At 4.6 m, weathering dominated due to interaction with CO<inf>2</inf> and infiltrating water. Prevalent high pH (7.9–8.6) at all three depths in association with strong oxidizing condition (at 4.6 m) during the drier months seem to play a crucial role in desorption based As release. Multivariate analyses revealed that redox potential (ORP) remains the primary controller of As release at all three depths. With depth, stronger anoxic conditions resulted in the dominance of reductive hydrolysis leading to a co-occurrence scenario of As (max 4.6 μgL⁻¹) with Zn (max 2514 μgL⁻¹) and Pb (max 740 μL⁻¹) with influences of anthropogenic modes of activities like agriculture and dry deposition from a brick kiln. Multi-element enrichment is an emerging concern but the bigger picture would be to understand the peculiarities of individual aquifers, as a generalization can lead to missing a ton of information. In this regard, long-term multilevel monitoring can help in the predictive understanding of the vertical stratification and co-occurrences of multi-metals that can subsequently be applied for water production at the safer depths.