Non-thermal magnetic deicing using two-dimensional chromium telluride
Source
Journal of Materials Chemistry C
ISSN
20507526
Date Issued
2024-10-01
Author(s)
Chowde Gowda, Chinmayee
Kartsev, Alexey
Tiwari, Nishant
Safronov, Alexander A.
Roy, Ajit K.
Ajayan, Pulickel M.
Galvão, Douglas S.
Tiwary, Chandra Sekhar
Abstract
Two-dimensional (2D) chromium telluride Cr<inf>2</inf>Te<inf>3</inf> exhibits strong ferromagnetic ordering with high coercivity at low temperatures and paramagnetic behavior when approaching room temperature. The spin states of monolayer Cr<inf>2</inf>Te<inf>3</inf> show ferromagnetic ordering in the ground state. In situ Raman analysis reveals a reversible structure transformation and hence proves ferromagnetic to paramagnetic transition during low-temperature heating cycles (0-25 °C). The magnetic phase transition near room temperature in 2D Cr<inf>2</inf>Te<inf>3</inf> prompted an exploratory study of these layered materials for energy application. We demonstrate that the low-temperature ferromagnetic behavior can be used to magnetically deice material surfaces using an external magnetic source, avoiding the use of harsh chemicals and high temperatures. The hydrophobic nature and dipole interactions of H<inf>2</inf>O molecules with the surface of the 2D Cr<inf>2</inf>Te<inf>3</inf> coating aid in the condensation of ice droplets formed on the surfaces. First-principles calculations also confirm the observed crystal structure, surface interaction, and magnetic properties of 2D Cr<inf>2</inf>Te<inf>3</inf>
