Salinity and temperature profiling for the submarine groundwater discharge simulations: Quantification through heat and solute transport model

Developed coastal regions are the hotspots for contaminated groundwater discharge, affecting sensitive marine ecosystems. The present study aims to identify submarine groundwater discharge (SGD) locations and quantify the contaminant load reaching to the western coast of India (Gujarat coast) using stable isotopes, seepage meter, heat and solute transport model. The coastal aquifers are highly enriched in trace metals due to various active natural processes and anthropogenic activities across the coast. Terrestrial and recirculated SGD was a significant contributor to flow and metal load, which ranged from 1.04 to 181.1 m³.year⁻¹ and 0–77.41 kg.year^-1, respectively. The highest estimated SGD in the Gujarat coast was relatively less than the SGD reported in the Bay of Bengal and comparable to the South Chennai coast. The order of metal flux found in the study was Zn > Fe > Cr > Pb > Ni > Cu > Mn, whereas the highest flux of Zn (77.41 kg. year⁻¹) was reported at Fansa beach, which was 7x Fe-flux and 45 x Cr-flux, respectively. Higher micronutrients (Fe and Zn) load in the southern coast leads to increased vulnerability of eutrophication, algal blooms and biotic ligand formation in aquatic species. This enrichment of micronutrients in the coastal ecosystem was evident by the growth of seaweeds on the seabed at SGD identified locations.